Au-Catalyzed Formation of Functionalized Quinolines from 2-Alkynyl Alkyl Azides Derivatives

Colombe Gronnier 1 Guillaume Boissonnat 1 Fabien Gagosz 1
1 DCSO - Laboratoire de synthèse organique
Abstract : A new method for converting 2-alkynyl arylazide derivatives into functionalized polysubstituted quinolines following a gold-catalyzed 1,3-acetoxy shift/cyclization/1,2-group shift sequence has been developed. This transformation proceeds under mild reaction conditions, is efficient, and tolerates a large variety of functional groups.
Document type :
Journal articles
Complete list of metadatas
https://hal-polytechnique.archives-ouvertes.fr/hal-00966614
Contributor : Denis Roura <>
Submitted on : Wednesday, March 26, 2014 - 9:46:28 PM
Last modification on : Thursday, February 7, 2019 - 5:16:35 PM

Identifiers

Collections

CNRS | X | X-DCSO | PARISTECH | INC-CNRS | X-DEP-CHIM

Citation

Colombe Gronnier, Guillaume Boissonnat, Fabien Gagosz. Au-Catalyzed Formation of Functionalized Quinolines from 2-Alkynyl Alkyl Azides Derivatives. Organic Letters, American Chemical Society, 2013, 15 (16), pp.4234-4237. ⟨10.1021/ol4019634⟩. ⟨hal-00966614⟩

Export

BibTeX TEI DC DCterms EndNote

Share

Metrics

Record views

123

Contact

Informations

CCSD