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Au-Catalyzed Formation of Functionalized Quinolines from 2-Alkynyl Alkyl Azides Derivatives

Colombe Gronnier 1 Guillaume Boissonnat 1 Fabien Gagosz 1
1 DCSO - Laboratoire de synthèse organique
Abstract : A new method for converting 2-alkynyl arylazide derivatives into functionalized polysubstituted quinolines following a gold-catalyzed 1,3-acetoxy shift/cyclization/1,2-group shift sequence has been developed. This transformation proceeds under mild reaction conditions, is efficient, and tolerates a large variety of functional groups.
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https://hal-polytechnique.archives-ouvertes.fr/hal-00966614
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Submitted on : Wednesday, March 26, 2014 - 9:46:28 PM
Last modification on : Thursday, March 5, 2020 - 6:26:55 PM

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CNRS | X | X-DCSO | INC-CNRS | X-DEP-CHIM

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Colombe Gronnier, Guillaume Boissonnat, Fabien Gagosz. Au-Catalyzed Formation of Functionalized Quinolines from 2-Alkynyl Alkyl Azides Derivatives. Organic Letters, American Chemical Society, 2013, 15 (16), pp.4234-4237. ⟨10.1021/ol4019634⟩. ⟨hal-00966614⟩

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