Abstract : A modular, convergent, and operationally simple route to trifluoromethyl alkenes and vinyl fluorides involving a unique carbon-oxygen bond homolysis is reported. Highly functionalized trifluoromethyl alkenes and vinyl fluorides were obtained in good yields and good selectivity.
https://hal-polytechnique.archives-ouvertes.fr/hal-00967571 Contributor : Denis RouraConnect in order to contact the contributor Submitted on : Saturday, March 29, 2014 - 12:01:48 PM Last modification on : Thursday, December 9, 2021 - 2:26:02 PM
Laurent Debien, Béatrice Quiclet-Sire, Samir S. Zard. A convergent, unified approach to functionalized fluoro- and trifluoromethyl alkenes.. Organic Letters, American Chemical Society, 2012, 14 (19), pp.5118-21. ⟨10.1021/ol3023903⟩. ⟨hal-00967571⟩