A convergent, unified approach to functionalized fluoro- and trifluoromethyl alkenes.

Abstract : A modular, convergent, and operationally simple route to trifluoromethyl alkenes and vinyl fluorides involving a unique carbon-oxygen bond homolysis is reported. Highly functionalized trifluoromethyl alkenes and vinyl fluorides were obtained in good yields and good selectivity.
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Submitted on : Saturday, March 29, 2014 - 12:01:48 PM
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Laurent Debien, Béatrice Quiclet-Sire, Samir Zard. A convergent, unified approach to functionalized fluoro- and trifluoromethyl alkenes.. Organic Letters, American Chemical Society, 2012, 14 (19), pp.5118-21. ⟨10.1021/ol3023903⟩. ⟨hal-00967571⟩

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