Gold(I)-catalyzed [4+2] cycloaddition of N-(hex-5-enynyl) tert-butyloxycarbamates

Andrea Buzas; Florin Istrate; X. Le Goff; Yann Odabachian; Fabien Gagosz

doi:10.1016/j.jorganchem.2008.11.004

Journal articles

Gold(I)-catalyzed [4+2] cycloaddition of N-(hex-5-enynyl) tert-butyloxycarbamates

Andrea Buzas ¹ Florin Istrate ¹ X. Le Goff ² Yann Odabachian ¹ Fabien Gagosz ¹

1 DCSO - Laboratoire de synthèse organique

2 DCPH - Laboratoire Hétéroéléments et Coordination

Abstract : A study concerning the gold(I)-catalyzed transformation of N-(hex-5-enynyl) tert-butyloxycarbamates is described. The mild conditions employed allow the moderately efficient but stereoselective synthesis of a range of bicyclic carbamates following a formal [4+2] cycloaddition process.

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Journal articles

Domain :

Chemical Sciences / Organic chemistry

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https://hal-polytechnique.archives-ouvertes.fr/hal-00968361
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Submitted on : Monday, March 31, 2014 - 9:18:58 PM
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Gold(I)-catalyzed [4+2] cycloaddition of N-(hex-5-enynyl) tert-butyloxycarbamates

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Gold(I)-catalyzed [4+2] cycloaddition of N-(hex-5-enynyl) tert-butyloxycarbamates

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