Gold(I)-catalyzed [4+2] cycloaddition of N-(hex-5-enynyl) tert-butyloxycarbamates

Andrea Buzas 1 Florin Istrate 1 Xavier Le Goff 2 Yann Odabachian 1 Fabien Gagosz 1
1 DCSO - Laboratoire de synthèse organique
2 DCPH - Laboratoire Hétéroéléments et Coordination
Abstract : A study concerning the gold(I)-catalyzed transformation of N-(hex-5-enynyl) tert-butyloxycarbamates is described. The mild conditions employed allow the moderately efficient but stereoselective synthesis of a range of bicyclic carbamates following a formal [4+2] cycloaddition process.
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Submitted on : Monday, March 31, 2014 - 9:18:58 PM
Last modification on : Tuesday, July 30, 2019 - 8:26:05 AM

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Andrea Buzas, Florin Istrate, Xavier Le Goff, Yann Odabachian, Fabien Gagosz. Gold(I)-catalyzed [4+2] cycloaddition of N-(hex-5-enynyl) tert-butyloxycarbamates. Journal of Organometallic Chemistry, Elsevier, 2009, 694 (4), pp.515-519. ⟨10.1016/j.jorganchem.2008.11.004⟩. ⟨hal-00968361⟩

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