Gold(I)-catalyzed [4+2] cycloaddition of N-(hex-5-enynyl) tert-butyloxycarbamates - École polytechnique Access content directly
Journal Articles Journal of Organometallic Chemistry Year : 2009

Gold(I)-catalyzed [4+2] cycloaddition of N-(hex-5-enynyl) tert-butyloxycarbamates

Abstract

A study concerning the gold(I)-catalyzed transformation of N-(hex-5-enynyl) tert-butyloxycarbamates is described. The mild conditions employed allow the moderately efficient but stereoselective synthesis of a range of bicyclic carbamates following a formal [4+2] cycloaddition process.

Dates and versions

hal-00968361 , version 1 (31-03-2014)

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Andrea Buzas, Florin M. Istrate, X. F Le Goff, Yann Odabachian, Fabien L. Gagosz. Gold(I)-catalyzed [4+2] cycloaddition of N-(hex-5-enynyl) tert-butyloxycarbamates. Journal of Organometallic Chemistry, 2009, 694 (4), pp.515-519. ⟨10.1016/j.jorganchem.2008.11.004⟩. ⟨hal-00968361⟩
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