Skip to Main content Skip to Navigation
Journal articles

Unified, radical-based approach for the synthesis of spiroketals.

Abstract : [reaction: see text] Functionalization of S-(3-chloro-2-oxo-propyl)-O-ethyl xanthate 1 by two consecutive xanthate transfer reactions, followed by spirocyclization of the resulting dihydroxy ketones, provides a flexible and highly convergent access to diversely substituted spiroketals, containing five-, six-, and seven-membered rings.
Document type :
Journal articles
Complete list of metadatas

https://hal-polytechnique.archives-ouvertes.fr/hal-00969144
Contributor : Denis Roura <>
Submitted on : Wednesday, April 2, 2014 - 10:32:42 AM
Last modification on : Thursday, March 5, 2020 - 6:27:14 PM

Identifiers

Collections

Citation

Michiel de Greef, Samir Z. Zard. Unified, radical-based approach for the synthesis of spiroketals.. Organic Letters, American Chemical Society, 2007, 9 (9), pp.1773-1776. ⟨10.1021/ol070488+⟩. ⟨hal-00969144⟩

Share

Metrics

Record views

147