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A concise synthesis of an advanced Clerodin intermediate through a Vaultier tandem reaction

Jean-Yves Lallemand 1, 2 Yvan Six 1, 2 Louis Ricard 3
1 ICSN - Institut de Chimie des Substances Naturelles
2 DCSO - Laboratoire de synthèse organique
3 DCPH - Laboratoire Hétéroéléments et Coordination
Abstract : A highly functionalised precursor of the antifeedant natural product Clerodin has been synthesised with good diastereocontrol. Key steps include a three-component version of the Vaultier tandem sequence, and an oxidative decarboxylation with a simple experimental procedure.
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https://hal-polytechnique.archives-ouvertes.fr/hal-00969327
Contributor : Denis Roura <>
Submitted on : Wednesday, April 2, 2014 - 1:30:21 PM
Last modification on : Monday, June 22, 2020 - 12:08:08 PM

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CNRS | X-DCSO | X | X-DCPH | ICSN | INC-CNRS | X-DEP-CHIM

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Jean-Yves Lallemand, Yvan Six, Louis Ricard. A concise synthesis of an advanced Clerodin intermediate through a Vaultier tandem reaction. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2002, pp.503-513. ⟨10.1002/1099-0690(20022)2002:3<503::AID-EJOC503>3.0.CO;2-6⟩. ⟨hal-00969327⟩

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