A concise synthesis of an advanced Clerodin intermediate through a Vaultier tandem reaction

Abstract : A highly functionalised precursor of the antifeedant natural product Clerodin has been synthesised with good diastereocontrol. Key steps include a three-component version of the Vaultier tandem sequence, and an oxidative decarboxylation with a simple experimental procedure.
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Submitted on : Wednesday, April 2, 2014 - 1:30:21 PM
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Jean-Yves Lallemand, Yvan Six, Louis Ricard. A concise synthesis of an advanced Clerodin intermediate through a Vaultier tandem reaction. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2002, pp.503-513. ⟨10.1002/1099-0690(20022)2002:3<503::AID-EJOC503>3.0.CO;2-6⟩. ⟨hal-00969327⟩

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