α-Scission of sulfonyl radicals: a versatile process for organic synthesis

Frédéric Bertrand; Frédéric Le Guyader; Lucia Liguori; Gilles Ouvry; Béatrice Quiclet-Sire; Stéphanie Seguin; Samir Z. Zard

doi:10.1016/S1387-1609(01)01270-1

Journal articles

α-Scission of sulfonyl radicals: a versatile process for organic synthesis

Frédéric Bertrand ¹ Frédéric Le Guyader ¹ Lucia Liguori ¹ Gilles Ouvry ² Béatrice Quiclet-Sire ^{1, 2} Stéphanie Seguin ¹ Samir Z. Zard ^{1, 2}

1 ICSN - Institut de Chimie des Substances Naturelles

2 DCSO - Laboratoire de synthèse organique

Abstract : The reversible addition of aliphatic radicals to sulphur dioxide can be exploited to design a variety of tin-free chain reactions. This brief review summarises some of the possibilities, namely radical allylation, vinylation, alkynylation, and azidation of various substrates.

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α-Scission of sulfonyl radicals: a versatile process for organic synthesis

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α-Scission of sulfonyl radicals: a versatile process for organic synthesis

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