Divergent Product Selectivity in Gold- versus Silver-Catalyzed Reaction of 2-Propynyloxy-6-fluoropyridines with Arylamines

Colombe Gronnier 1 Pierre Faudot Dit Bel 1 Guilhem Henrion 1 Søren Krämer 1 Fabien Gagosz 1
1 DCSO - Laboratoire de synthèse organique
Abstract : A study of the reaction of easily accessible 2-propynyloxy-6-fluoropyridines with arylamines under gold or silver catalysis is described. It has been shown that two types of isomeric oxazolopyridine imine derivatives, which represent unusual heterocyclic motifs, can be selectively obtained in moderate to excellent yields depending on the nature of the metal employed.
Document type :
Journal articles
Complete list of metadatas
https://hal-polytechnique.archives-ouvertes.fr/hal-00995310
Contributor : Denis Roura <>
Submitted on : Friday, May 23, 2014 - 9:55:38 AM
Last modification on : Thursday, February 7, 2019 - 5:16:34 PM

Identifiers

Collections

CNRS | X-DCSO | X | PARISTECH | INC-CNRS | X-DEP-CHIM

Citation

Colombe Gronnier, Pierre Faudot Dit Bel, Guilhem Henrion, Søren Krämer, Fabien Gagosz. Divergent Product Selectivity in Gold- versus Silver-Catalyzed Reaction of 2-Propynyloxy-6-fluoropyridines with Arylamines. Organic Letters, American Chemical Society, 2014, 16 (8), pp.2092-2095. ⟨10.1021/ol500939v⟩. ⟨hal-00995310⟩

Export

BibTeX TEI DC DCterms EndNote

Share

Metrics

Record views

163

Contact

Informations

CCSD