Abstract : Unprecedented examples of a synthetically useful radical ring closure onto a pyrimidine nitrogen leading to novel, highly functionalized bi- and tricyclic pyrimidone structures are reported. An unexpected hydrogen atom translocation prior to the cyclization step was observed in some cases.
Type de document :
Article dans une revue
Organic Letters, American Chemical Society, 2014, 16 (11), pp.2966-2969. 〈10.1021/ol501104h〉
https://hal-polytechnique.archives-ouvertes.fr/hal-01017929
Contributeur : Denis Roura
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Soumis le : jeudi 3 juillet 2014 - 14:02:49
Dernière modification le : jeudi 12 avril 2018 - 01:49:11
Ling Qin, Zhibo Liu, Samir Zard. Carbon Radical Attack on a Pyrimidine Nitrogen. An Unusual Entry into Polycyclic Aminopyrimidones. Organic Letters, American Chemical Society, 2014, 16 (11), pp.2966-2969. 〈10.1021/ol501104h〉. 〈hal-01017929〉
