Nitrile Synthesis through Catalyzed Cascades Involving Acid-Nitrile Exchange

Damien Cartigny; Aurélie dos Santos; Laurent El Kaim; Laurence Grimaud; Roland Jacquot; Philippe Marion

Nitrile Synthesis through Catalyzed Cascades Involving Acid-Nitrile Exchange

Damien Cartigny ¹ Aurélie dos Santos ² Laurent El Kaim ^{2, *} Laurence Grimaud ^{3, *} Roland Jacquot ⁴ Philippe Marion ^{4, *}

* Corresponding author

1 E2P2L - Eco-Efficient Products and Processes Laboratory

2 DCSO - Laboratoire de synthèse organique

3 PASTEUR - Processus d'Activation Sélective par Transfert d'Energie Uni-électronique ou Radiatif (UMR 8640)

4 Solvay Recherches & Innovation Centre de Lyon

Abstract : Irreversible acid-nitrile exchange reactions using both glutaronitrile and (phenylsulfonyl)acetonitrile may be catalyzed by Lewis acids. Whereas a cyclization towards imides displaces the equilibria in the reaction with dinitriles, a decarboxylation step is involved when using the (phenylsulfonyl)acetonitrile.

Document type :

Journal articles

Domain :

Chemical Sciences / Organic chemistry

Complete list of metadatas

https://hal-polytechnique.archives-ouvertes.fr/hal-01044733
Contributor : Denis Roura <>
Submitted on : Thursday, July 24, 2014 - 10:11:36 AM
Last modification on : Tuesday, May 14, 2019 - 10:58:12 AM

Nitrile Synthesis through Catalyzed Cascades Involving Acid-Nitrile Exchange

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Nitrile Synthesis through Catalyzed Cascades Involving Acid-Nitrile Exchange

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