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Nitrile Synthesis through Catalyzed Cascades Involving Acid-Nitrile Exchange

Damien Cartigny 1 Aurélie dos Santos 2 Laurent El Kaim 2, * Laurence Grimaud 3, * Roland Jacquot 4 Philippe Marion 4, *
* Corresponding author
1 E2P2L - Eco-Efficient Products and Processes Laboratory
2 DCSO - Laboratoire de synthèse organique
3 PASTEUR - Processus d'Activation Sélective par Transfert d'Energie Uni-électronique ou Radiatif (UMR 8640)
4 Solvay Recherches & Innovation Centre de Lyon
Abstract : Irreversible acid-nitrile exchange reactions using both glutaronitrile and (phenylsulfonyl)acetonitrile may be catalyzed by Lewis acids. Whereas a cyclization towards imides displaces the equilibria in the reaction with dinitriles, a decarboxylation step is involved when using the (phenylsulfonyl)acetonitrile.
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https://hal-polytechnique.archives-ouvertes.fr/hal-01044733
Contributor : Denis Roura <>
Submitted on : Thursday, July 24, 2014 - 10:11:36 AM
Last modification on : Thursday, December 10, 2020 - 12:38:41 PM

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CNRS | X | X-DCSO | UPMC | PASTEUR_UMR8640 | ENS-PARIS | INC-CNRS | X-DEP-CHIM | SORBONNE-UNIVERSITE | SU-SCIENCES | PSL | SU-TI

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Damien Cartigny, Aurélie dos Santos, Laurent El Kaim, Laurence Grimaud, Roland Jacquot, et al.. Nitrile Synthesis through Catalyzed Cascades Involving Acid-Nitrile Exchange. SYNTHESIS, Georg Thieme Verlag, 2014, 46 (13), pp.1802-1806. ⟨10.1055/s-0033-1341227⟩. ⟨hal-01044733⟩

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