Nitrile Synthesis through Catalyzed Cascades Involving Acid-Nitrile Exchange

Abstract : Irreversible acid-nitrile exchange reactions using both glutaronitrile and (phenylsulfonyl)acetonitrile may be catalyzed by Lewis acids. Whereas a cyclization towards imides displaces the equilibria in the reaction with dinitriles, a decarboxylation step is involved when using the (phenylsulfonyl)acetonitrile.
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https://hal-polytechnique.archives-ouvertes.fr/hal-01044733
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Submitted on : Thursday, July 24, 2014 - 10:11:36 AM
Last modification on : Tuesday, May 14, 2019 - 10:58:12 AM

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Damien Cartigny, Aurélie dos Santos, Laurent El Kaim, Laurence Grimaud, Roland Jacquot, et al.. Nitrile Synthesis through Catalyzed Cascades Involving Acid-Nitrile Exchange. SYNTHESIS, Georg Thieme Verlag, 2014, 46 (13), pp.1802-1806. ⟨10.1055/s-0033-1341227⟩. ⟨hal-01044733⟩

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