Reductive Passerini/Tsuji-Trost Strategy towards beta,gamma-Unsaturated Amides

Abstract : The Passerini reaction of α,β-unsaturated aldehydes with formic acid followed by a reductive Tsuji-Trost reaction affords β,γ-unsaturated amides. The overall process may be viewed as a one-carbon homologation of unsaturated aldehydes into amides.
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Submitted on : Thursday, September 18, 2014 - 2:32:52 PM
Last modification on : Thursday, February 7, 2019 - 2:45:10 PM

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Aurélie dos Santos, Laurent El Kaim. Reductive Passerini/Tsuji-Trost Strategy towards beta,gamma-Unsaturated Amides. SYNLETT, Georg Thieme Verlag, 2014, 25 (13), pp.1901-1903. ⟨10.1055/s-0033-1340187⟩. ⟨hal-01065732⟩

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