Nanometric Resolved Luminescence in h-BN Flakes: Excitons and Stacking Order

Romain Bourrellier 1 Michele Amato 2, 1, 3 Luiz Henrique Galvao Tizei 1 Christine Giorgetti 4 Alexandre Gloter 1 Malcolm I. Heggie 5 Katia March 1 Odile Stephan 1 Lucia Reining 4 Mathieu Kociak 1 Alberto Zobelli 1
1 LPS - Laboratoire de Physique des Solides
2 IEF
3 ST - Spectroscopie théorique
LSI - UMR 7642 - Laboratoire des Solides Irradiés
4 LSI - UMR 7642 - Laboratoire des Solides Irradiés
5 UNIS - University of Surrey
Abstract : The strong excitonic emission of hexagonal boron nitride (h-BN) makes this material one of the most promising candidate for light emitting devices in the far ultraviolet (UV). However, single excitons occur only in perfect monocrystals that are extremely hard to synthesize, while regular h-BN samples present a complex emission spectrum with several additional peaks. The microscopic origin of these additional emissions has not yet been understood. In this work we address this problem using an experimental and theoretical approach that combines nanometric resolved cathodoluminescence, high resolution transmission electron microscopy and state of the art theoretical spectroscopy methods. We demonstrate that emission spectra are strongly inhomogeneus within individual few layer flakes and that additional excitons occur at structural deformations, such as faceted plane folds, that lead to local changes of the h-BN layers stacking order.
Keywords : boron nitride cathodoluminescence excitons theoretical spectroscopy electron microscopy
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Article dans une revue
ACS photonics, American Chemical Society,, 2014, 1, pp.857-862. 〈10.1021/ph500141j〉
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https://hal-polytechnique.archives-ouvertes.fr/hal-01083371
Contributeur : Christine Giorgetti <>
Soumis le : lundi 17 novembre 2014 - 11:13:09
Dernière modification le : jeudi 10 mai 2018 - 01:58:42

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Romain Bourrellier, Michele Amato, Luiz Henrique Galvao Tizei, Christine Giorgetti, Alexandre Gloter, et al.. Nanometric Resolved Luminescence in h-BN Flakes: Excitons and Stacking Order. ACS photonics, American Chemical Society,, 2014, 1, pp.857-862. 〈10.1021/ph500141j〉. 〈hal-01083371〉

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