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Passerini/Tsuji-Trost strategies towards achieving lactams and cyclopentane derivatives.

Marie Cordier 1 Aurélie dos Santos 2, 3 Laurent El Kaim 3, 2 Noisette Narboni 3, 2
1 LCM - Laboratoire de chimie moléculaire
2 SOR - Synthèse Organique et Réactivité
3 DCSO - Laboratoire de synthèse organique
Abstract : The Passerini reaction of α,β-unsaturated aldehydes affords suitable substrates for the Tsuji-Trost reaction with various carbon based-nucleophiles. The resulting α,β-unsaturated amides may be cyclized to lactams or converted into cyclopentane derivatives if bis-nucleophiles are used in the Tsuji-Trost step.
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https://hal-polytechnique.archives-ouvertes.fr/hal-01152233
Contributor : Denis Roura <>
Submitted on : Friday, May 15, 2015 - 4:01:27 PM
Last modification on : Thursday, March 5, 2020 - 6:30:57 PM

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Marie Cordier, Aurélie dos Santos, Laurent El Kaim, Noisette Narboni. Passerini/Tsuji-Trost strategies towards achieving lactams and cyclopentane derivatives.. Chemical Communications, Royal Society of Chemistry, 2015, 51 (29), pp.6411-4. ⟨10.1039/C5CC00584A⟩. ⟨hal-01152233⟩

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