O-Ethyl-S-(1,2,2,2-Tetrafluoroethyl)-Dithiocarbonate: A Convenient Reagent for the Generation and Capture of 1,2,2,2-Tetra­fluoroethyl Radicals

David Clemente-Tejeda; Samir Zard

doi:10.1055/s-0035-1560539

O-Ethyl-S-(1,2,2,2-Tetrafluoroethyl)-Dithiocarbonate: A Convenient Reagent for the Generation and Capture of 1,2,2,2-Tetrafluoroethyl Radicals

David Clemente-Tejeda ¹ Samir Zard ¹

1 DCSO - Laboratoire de synthèse organique

Abstract : The synthesis of a new fluorinated reagent O-ethyl S-(1,2,2,2-tetrafluoroethyl) carbonodithioate (xanthate) and its use for the generation and capture of the hitherto unexplored 1,2,2,2-tetrafluoroethyl radicals is described. This reagent allows the convenient introduction of the rare CF3CHF motif onto various olefinic substrates with a high functional-group tolerance.

Type de document :

Article dans une revue

SYNLETT, Georg Thieme Verlag, 2015, 27 (01), 〈10.1055/s-0035-1560539〉

Domaine :

Chimie / Chimie organique

Liste complète des métadonnées

https://hal-polytechnique.archives-ouvertes.fr/hal-01276151
Contributeur : Denis Roura <>
Soumis le : jeudi 18 février 2016 - 20:10:47
Dernière modification le : jeudi 7 février 2019 - 14:44:58

O-Ethyl-S-(1,2,2,2-Tetrafluoroethyl)-Dithiocarbonate: A Convenient Reagent for the Generation and Capture of 1,2,2,2-Tetrafluoroethyl Radicals

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O-Ethyl-S-(1,2,2,2-Tetrafluoroethyl)-Dithiocarbonate: A Convenient Reagent for the Generation and Capture of 1,2,2,2-Tetra­fluoroethyl Radicals

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O-Ethyl-S-(1,2,2,2-Tetrafluoroethyl)-Dithiocarbonate: A Convenient Reagent for the Generation and Capture of 1,2,2,2-Tetrafluoroethyl Radicals