O-Ethyl-S-(1,2,2,2-Tetrafluoroethyl)-Dithiocarbonate: A Convenient Reagent for the Generation and Capture of 1,2,2,2-Tetra­fluoroethyl Radicals

Abstract : The synthesis of a new fluorinated reagent O-ethyl S-(1,2,2,2-tetrafluoroethyl) carbonodithioate (xanthate) and its use for the generation and capture of the hitherto unexplored 1,2,2,2-tetrafluo­roethyl radicals is described. This reagent allows the convenient introduction of the rare CF3CHF motif onto various olefinic substrates with a high functional-group tolerance.
Type de document :
Article dans une revue
SYNLETT, Georg Thieme Verlag, 2015, 27 (01), 〈10.1055/s-0035-1560539〉
Liste complète des métadonnées

https://hal-polytechnique.archives-ouvertes.fr/hal-01276151
Contributeur : Denis Roura <>
Soumis le : jeudi 18 février 2016 - 20:10:47
Dernière modification le : jeudi 10 mai 2018 - 02:07:51

Identifiants

Citation

David Clemente-Tejeda, Samir Zard. O-Ethyl-S-(1,2,2,2-Tetrafluoroethyl)-Dithiocarbonate: A Convenient Reagent for the Generation and Capture of 1,2,2,2-Tetra­fluoroethyl Radicals. SYNLETT, Georg Thieme Verlag, 2015, 27 (01), 〈10.1055/s-0035-1560539〉. 〈hal-01276151〉

Partager

Métriques

Consultations de la notice

126