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Journal articles
Methoxycarbonyl migration in 3-methylene-1,4-cyclohexadienes. An extension of the von Auwers rearrangement
Abstract : Upon heating, 3-methylene-1,4-cyclohexadienes possessing an alkoxycarbonyl substituent in position 6 undergo rearrangement and concomitant aromatization to give the corresponding arylacetates. This transformation represents a modification of the von Auwers rearrangement and proceeds by a radical chain mechanism. The intermediate alkoxycarbonyl radical can be intercepted allowing further useful synthetic variations.
https://hal-polytechnique.archives-ouvertes.fr/hal-01444340
Contributor : Denis Roura <>
Submitted on : Monday, January 23, 2017 - 10:38:54 PM
Last modification on : Thursday, March 5, 2020 - 6:34:25 PM
Contributor : Denis Roura <>
Submitted on : Monday, January 23, 2017 - 10:38:54 PM
Last modification on : Thursday, March 5, 2020 - 6:34:25 PM