Palladium-catalysed O -Allylation of α-Hydroxyphosphonates: An Expedient Entry into Phosphono-oxaheterocycles

Abstract : We report here an unprecedented palladium‐catalysed O‐allylation of α‐hydroxyphosphonates. The method was eventually included in a sequential Pudovik/Tsuji‐Trost type O‐allylation/Ring‐Closing Metathesis to afford a variety of phosphorylated heterocycles of various sizes ranging from 5 to 16 starting from readily available aldehydes.
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Submitted on : Saturday, April 6, 2019 - 11:35:22 AM
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Mansour Dolé Kerim, Martin Cattoen, Nicolas Fincias, Aurélie Dos santos, Stellios Arseniyadis, et al.. Palladium-catalysed O -Allylation of α-Hydroxyphosphonates: An Expedient Entry into Phosphono-oxaheterocycles. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2018, 360 (3), pp.449-454. ⟨https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.201701150⟩. ⟨10.1002/adsc.201701150⟩. ⟨hal-02091718⟩

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