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Passerini/Tsuji-Trost Strategy towards Pyrrole Derivatives

Abstract : The Passerini reaction of α,β‐unsaturated aldehydes affords suitable substrates for a Tsuji–Trost reaction with NH‐enamines. The latter behave as a 1,3‐bisnucleophile, which leads to the formation of pyrrole derivatives with five points of diversity through a Tsuji–Trost/Michael addition/aromatization cascade.
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Contributor : Aurélien Arnoux Connect in order to contact the contributor
Submitted on : Tuesday, April 9, 2019 - 2:49:32 PM
Last modification on : Wednesday, May 11, 2022 - 12:06:07 PM



Noisette Narboni, Laurent El Kaim. Passerini/Tsuji-Trost Strategy towards Pyrrole Derivatives. European Journal of Organic Chemistry, 2017, 2017 (29), pp.4242-4246. ⟨10.1002/ejoc.201700653⟩. ⟨hal-02094146⟩



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