 |
École polytechnique Open archive |  |
 |
Journal articles
Palladium triggered diene formation from nitro allylic compounds: a versatile entry into naphthalene derivatives
Abstract : Nitro allylic derivatives were converted into dienes through the elimination of the nitro group under basic treatment, in the presence of a palladium catalyst. This reaction probably involves the formation of a palladium π-allyl complex followed by a base-promoted β-hydride elimination. This reaction, combined with the condensation of ketones with nitromethane and the functionalization of the resulting nitrocycloalkenes, constitutes a very powerful synthetic tool for the formation of dienes. Particular attention has been brought to the application of this methodology to the formation of 1-substituted naphthalenes from 1-tetralone.
https://hal-polytechnique.archives-ouvertes.fr/hal-02094211
Contributor : Aurélien Arnoux Connect in order to contact the contributor
Submitted on : Tuesday, April 9, 2019 - 3:06:52 PM
Last modification on : Friday, December 3, 2021 - 11:34:11 AM
Contributor : Aurélien Arnoux Connect in order to contact the contributor
Submitted on : Tuesday, April 9, 2019 - 3:06:52 PM
Last modification on : Friday, December 3, 2021 - 11:34:11 AM