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Journal Articles SYNLETT Year : 2018

A Direct Xanthate-Based Route to γ-Thiolactones

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Abstract

The first examples of direct synthesis of γ-thiolactones by addition of a thiolactone-based radical are described. Mono- and bis-γ-thiolactones can be obtained by a dilauroyl peroxide initiated addition of thiolactone xanthate to various alkenes and α,ω-dienes. The process is modular and exhibits a high functional group tolerance.
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hal-02094239 , version 1 (09-04-2019)

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Raphaël Simonet-Davin, Samir Z. Zard. A Direct Xanthate-Based Route to γ-Thiolactones. SYNLETT, 2018, 29 (06), pp.815-819. ⟨10.1055/s-0036-1590987⟩. ⟨hal-02094239⟩
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