A Direct Xanthate-Based Route to γ-Thiolactones

Abstract : The first examples of direct synthesis of γ-thiolactones by addition of a thiolactone-based radical are described. Mono- and bis-γ-thiolactones can be obtained by a dilauroyl peroxide initiated addition of thiolactone xanthate to various alkenes and α,ω-dienes. The process is modular and exhibits a high functional group tolerance.
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https://hal-polytechnique.archives-ouvertes.fr/hal-02094239
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Submitted on : Tuesday, April 9, 2019 - 3:14:59 PM
Last modification on : Friday, April 12, 2019 - 1:31:50 AM

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Raphaël Simonet-Davin, Samir Zard. A Direct Xanthate-Based Route to γ-Thiolactones. SYNLETT, Georg Thieme Verlag, 2018, 29 (06), pp.815-819. ⟨https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0036-1590987⟩. ⟨10.1055/s-0036-1590987⟩. ⟨hal-02094239⟩

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