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Journal Articles Tetrahedron Year : 2018

Xanthate-mediated intermolecular alkylation of pyrazines

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Abstract

An expedient approach for the intermolecular C-H functionalization of pyrazines and other heteroarenes by the radical chemistry of xanthates is reported. Incorporation of a multitude of functional alkyl groups onto these heteroarenes proceeds in good yield and good to excellent regioselectivity, leading to highly functionalized heteroaromatics.
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hal-02094257 , version 1 (09-04-2019)

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Qi Huang, Qi Qin, Samir Z. Zard. Xanthate-mediated intermolecular alkylation of pyrazines. Tetrahedron, 2018, 74 (40), pp.5804-5817. ⟨10.1016/j.tet.2018.08.040⟩. ⟨hal-02094257⟩
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