A Passerini/Tsuji-Trost access to dienamide derivatives

Abstract : The Passerini reaction of α, β-unsaturated aldehydes affords allylic acetates which may be involved in Tsuji-Trost elimations towards conjugated dienamides. The interest of these 2,4-dienamides has been demonstrated in several TiCl4 triggered Diels-Alder reactions with N-phenylmaleimide.
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https://hal-polytechnique.archives-ouvertes.fr/hal-02096732
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Submitted on : Thursday, April 11, 2019 - 3:19:53 PM
Last modification on : Wednesday, July 3, 2019 - 10:48:05 AM

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Sihem Dali Youcef, Mansour Dolé Kerim, Hocine Ilitki, Laurent El Kaim. A Passerini/Tsuji-Trost access to dienamide derivatives. Tetrahedron Letters, Elsevier, 2019, 60 (2), pp.102-105. ⟨10.1016/j.tetlet.2018.11.068⟩. ⟨hal-02096732⟩

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