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A Passerini/Tsuji-Trost access to dienamide derivatives

Sihem Dali youcef 1, 2 Mansour Dolé Kerim 1 Hocine Ilitki 2, * Laurent El Kaim 3, 1 
* Corresponding author
1 DCSO - Laboratoire de synthèse organique
2 USTO MB - Université des sciences et de la Technologie d'Oran Mohamed Boudiaf [Oran]
3 ENSTA Paris - École Nationale Supérieure de Techniques Avancées
Abstract : The Passerini reaction of α, β-unsaturated aldehydes affords allylic acetates which may be involved in Tsuji-Trost elimations towards conjugated dienamides. The interest of these 2,4-dienamides has been demonstrated in several TiCl4 triggered Diels-Alder reactions with N-phenylmaleimide.
Keywords : Passerini Tsuji-Trost 1.3-Diene Diels-Alder Isocyanide
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https://hal-polytechnique.archives-ouvertes.fr/hal-02096732
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Submitted on : Thursday, April 11, 2019 - 3:19:53 PM
Last modification on : Wednesday, May 11, 2022 - 12:06:07 PM

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Sihem Dali youcef, Mansour Dolé Kerim, Hocine Ilitki, Laurent El Kaim. A Passerini/Tsuji-Trost access to dienamide derivatives. Tetrahedron Letters, Elsevier, 2019, 60 (2), pp.102-105. ⟨10.1016/j.tetlet.2018.11.068⟩. ⟨hal-02096732⟩

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