A Passerini/Tsuji-Trost access to dienamide derivatives

Sihem Dali Youcef; Mansour Dolé Kerim; Hocine Ilitki; Laurent El Kaim

doi:10.1016/j.tetlet.2018.11.068

Journal articles

A Passerini/Tsuji-Trost access to dienamide derivatives

Sihem Dali Youcef ^{1, 2} Mansour Dolé Kerim ¹ Hocine Ilitki ^{2, *} Laurent El Kaim ^{3, 1}

* Corresponding author

1 DCSO - Laboratoire de synthèse organique

2 USTO MB - Université des sciences et de la Technologie d'Oran Mohamed Boudiaf [Oran]

3 ENSTA Paris - École Nationale Supérieure de Techniques Avancées

Abstract : The Passerini reaction of α, β-unsaturated aldehydes affords allylic acetates which may be involved in Tsuji-Trost elimations towards conjugated dienamides. The interest of these 2,4-dienamides has been demonstrated in several TiCl4 triggered Diels-Alder reactions with N-phenylmaleimide.

Keywords : Passerini Tsuji-Trost 1.3-Diene Diels-Alder Isocyanide

Document type :

Journal articles

Domain :

Chemical Sciences / Organic chemistry

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https://hal-polytechnique.archives-ouvertes.fr/hal-02096732
Contributor : Aurélien Arnoux <>
Submitted on : Thursday, April 11, 2019 - 3:19:53 PM
Last modification on : Wednesday, July 3, 2019 - 10:48:05 AM

A Passerini/Tsuji-Trost access to dienamide derivatives

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