TitaniumSilicalite: A Novel Derivative in the Pentasil Family, Studies in Surface Science and Catalysis, vol.28, pp.129-136, 1986. ,
Liquid Phase Oxidation via Heterogeneous Catalysis: Organic Synthesis and Industrial Applications, 2013. ,
Oxidative Transformations of Organic Compounds Mediated by Redox Molecular Sieves, Angew. Chem. Int. Ed. Engl, vol.36, pp.1144-1163, 1997. ,
DOI : 10.1002/anie.199711441
Recent Developments in Liquid-Phase Selective Oxidation Using Environmentally Benign Oxidants and Mesoporous Metal Silicates, Catal. Sci. Technol, vol.4, pp.1869-1889, 2014. ,
DOI : 10.1039/c4cy00087k
Catalytic Oxidations with Hydrogen Peroxide as Oxidant, 1992. ,
Metal-Catalyzed Epoxidations of Alkenes with Hydrogen Peroxide, Chem. Rev, vol.103, pp.2457-2474, 2003. ,
DOI : 10.1002/chin.200338259
The Activity of Titanium Silicalite-1 (TS-1): Some Considerations on Its Origin, Kinet. Catal, vol.56, pp.450-455, 2015. ,
Transition-Metal Complexes for Liquid-Phase Catalytic Oxidation: Some Aspects of Industrial Reactions and of Emerging Technologies, Dalton Trans, pp.3289-3302, 2003. ,
Hybrid QM/MM Investigations into the Structure and Properties of Oxygen-Donating Species in TS-1, J. Phys. Chem. C, vol.112, pp.7173-7185, 2008. ,
On Silsesquioxanes' Accuracy as Molecular Models for ,
DOI : 10.1016/j.ccr.2009.09.031
, Silica-Grafted Complexes in Heterogeneous Catalysis, Coord. Chem. Rev, vol.254, pp.707-728, 2010.
Advances in Homogeneous and Heterogeneous Catalysis with MetalContaining Silsesquioxanes, Chem. -Eur. J, vol.6, pp.25-32, 2000. ,
DOI : 10.1002/(sici)1521-3765(20000103)6:1<25::aid-chem25>3.3.co;2-p
Silsesquioxanes as Molecular Analogues of Single-Site Heterogeneous Catalysts, Proc R Soc A, vol.468, pp.1968-1984, 2012. ,
DOI : 10.1098/rspa.2012.0113
URL : http://rspa.royalsocietypublishing.org/content/468/2143/1968.full.pdf
,
Anchored to Silanol-Functionalized Polyoxotungstates: Molecular Models for Single-Site Silica-Supported Vanadium Catalysts, ACS Catal, vol.5, pp.7415-7423, 2015. ,
Evidence of the Presence of Two Different Framework Ti(IV) Species in Ti?Silicalite-1 in Vacuo Conditions: An EXAFS and a Photoluminescence Study, J. Phys. Chem. B, vol.102, pp.6382-6390, 1998. ,
Characterization of Two Different Framework Titanium Sites and Quantification of Extra-Framework Species in TS-1 Silicalites, Stud. Surf. Sci. Catal, vol.101, pp.611-620, 1996. ,
,
Titanium Silsesquioxanes Grafted on Three-Dimensionally Netted Polysiloxanes: Catalytic Ensembles for Epoxidation of Alkenes with Aqueous Hydrogen Peroxide, Angew. Chem. Int. Ed, vol.41, pp.637-639, 2002. ,
,
An Efficient Hybrid, Nanostructured, Epoxidation Catalyst: Titanium Silsesquioxane-Polystyrene Copolymer ,
, Chem. -Eur. J, vol.13, pp.1210-1221, 2007.
Tripodal Titanium Silsesquioxane Complexes Immobilized in Polydimethylsiloxane (PDMS) Membrane: Selective Catalysts for Epoxidation of Cyclohexene and 1-Octene with Aqueous Hydrogen Peroxide, J. Catal, vol.273, pp.66-72, 2010. ,
Catalysis by Polyoxometalates ,
, , 2002.
Epoxidation of Olefins with Hydrogen Peroxide Catalyzed by Polyoxometalates, Coord. Chem. Rev, vol.249, pp.1944-1956, 2005. ,
Oxygenation of Methylarenes to Benzaldehyde Derivatives by a Polyoxometalate Mediated Electron Transfer-Oxygen Transfer Reaction in ,
, Aqueous Sulfuric Acid. J. Am. Chem. Soc, vol.137, pp.5916-5922, 2015.
Recent Advances in Polyoxometalate-Catalyzed Reactions ,
DOI : 10.1021/cr500390v
, Chem. Rev, vol.115, pp.4893-4962, 2015.
The Heteropolyoxotungstates: Relationships Between Routes of Formation and Structures, Rev. Inorg. Chem, vol.22, pp.63-112, 2011. ,
DOI : 10.1002/chin.200306218
Functionalization of Polyoxometalates: Towards Advanced Applications in Catalysis and Materials Science, Chem. Commun, pp.1837-1852, 2008. ,
Coordination Chemistry of Polyoxometalates: Rational Synthesis of the Mixed Organosilyl Derivatives of Trivacant Polyoxotungstates ?-A ,
, Chem.-Int. Ed. Engl, vol.35, pp.1961-1964, 1996.
,
Toward a Unified Identification of Ti Location in the MFI Framework of High-Ti-Loaded TS-1: Combined EXAFS, XANES, and DFT Study, J. Phys. Chem. C, vol.120, pp.20114-20124, 2016. ,
Synthesis and Structural Characterisation of Tripodal Titanium Silsesquioxane Complexes: A New Class of Highly Active Catalysts for Liquid Phase Alkene Epoxidation, Chem. Commun, vol.24, pp.2411-2412, 1997. ,
,
Modelling the Active Sites of Heterogeneous Titanium-Centred Epoxidation Catalysts with Soluble Silsesquioxane Analogues, Chem. Commun, vol.19, pp.1847-1848, 1997. ,
Solid State Structure of the Tantalum BisAryl Compounds Ta(OAr-2,6R 2 ) 3 (C 6 H 5 ) 2 (R = CH 3 , Pr i ,
, Lack of Correlation of M-OAr Distances and M-O-Ar Angles for Aryloxide Derivatives of Niobium(V) and Tantalum(V). Polyhedron, vol.9, pp.963-968, 1990.
Mono-and Dinuclear Silica-Supported Titanium(IV) Complexes and the Effect of TiOTi Connectivity on Reactivity, J. Am. Chem. Soc, vol.121, pp.7201-7210, 1999. ,
,
A Dimeric Titanium-Containing Polyoxometalate. Synthesis, Characterization, and Catalysis of H 2 O 2 -Based Thioether Oxidation, Inorg. Chem, vol.39, pp.3828-3837, 2000. ,
Synthesis, Characterization, and Reactivity of Ti(IV)-Monosubstituted Keggin Polyoxometalates, Inorg. Chem, vol.44, pp.1635-1642, 2005. ,
DOI : 10.1021/ic0490829
A Novel Ti-O-Ti Bonding Species Constructed in a Metal-Oxide Cluster, Ox)}, vol.2, issue.2 ,
,
, Epoxidation of Alkenes with Hydrogen Peroxide, J. Mol. Catal. Chem, vol.262, pp.25-29, 2007.
,
, Nonhydrolytic Sol?Gel Process: Aluminum Titanate Gels. Chem. Mater, vol.9, pp.1098-1102, 1997.
Olefin Epoxidation Catalyzed by an Air Stable-Supported Titanium Catalyst, J. Mol. Catal. Chem, vol.203, pp.145-152, 2003. ,
DOI : 10.1016/s1381-1169(03)00215-2
Silsesquioxane Chemistry, 4.: Silsesquioxane Complexes of Titanium(III) and Titanium(IV), J. Organomet. Chem, vol.620, issue.37, p.96, 1990. ,
Reinvestigation of Epoxidation Using Tungsten-Based Precursors and Hydrogen Peroxide in a Biphase Medium, Inorg. Chem, vol.30, pp.4409-4415, 1991. ,
Oxygen-Transfer from Inorganic and Organic Peroxides to Organic Substrates -A Common Mechanism, Angew. Chem.-Int. Ed, vol.21, pp.734-750, 1982. ,
DOI : 10.1002/anie.198207341
A New Peroxotungsten Heteropoly Anion with Special Oxidizing Properties: Synthesis and Structure of Tetrahexylammonium Tetra(Diperoxotungsto)Phosphate(3-), J. Mol. Catal, vol.32, pp.107-110, 1985. ,
From Polyoxometalates to Polyoxoperoxometalates and Back Again, Potential Applications. J. Mol. Catal. Chem, vol.250, pp.177-189, 2006. ,
Redistribution and Fluxionality in Heteropolyoxoperoxo Complexes, Dalton Trans, vol.33, pp.904-907, 2004. ,
DOI : 10.1039/b315879a
URL : https://hal.archives-ouvertes.fr/hal-00162378
, Bregeault, J. M. 31 P and 183 W NMR Spectroscopic Evidence for Novel
, ?yH 2 O/H 2 O 2 " System. Synthesis and X-Ray Structure of Tetrabutylammonium (?-Hydrogen phosphato)bis(?-peroxo)bis(oxoperoxotungstate)(2-): A Catalyst of Olefin Epoxidation in a Biphase Medium, Inorg. Chem, vol.33, pp.871-878, 1994.
Conception de polyoxométallates amphiphiles pour la catalyse d'oxydation en microémulsion, 2014. ,
, Olefin Epoxidation with
, Hydrogen Peroxide Catalyzed by Lacunary Polyoxometalate
, , vol.13, pp.639-648, 2007.
, Synthesis
IR) Evidence for the Formation of Superoxo Polytungstates, J. Am. Chem. Soc, vol.121, pp.977-984, 1999. ,
Mechanistic Insights into Alkene Epoxidation with H 2 O 2 by Ti-and Other TM-Containing Polyoxometalates: Role of the Metal Nature and Coordination Environment, J. Am. Chem. Soc, vol.132, pp.7488-7497, 2010. ,
Hydrogen Peroxide Activation over Ti IV : What Have We Learned from ,
DOI : 10.1002/ejic.201201396
Synthesis, Structural Characterization, and Catalytic Performance of Dititanium-Substituted ?-Keggin Silicotungstate, Studies on Ti-Containing Polyoxometalates, vol.45, pp.2347-2356, 2006. ,
DOI : 10.1021/ic052179q
Synthesis and Oxidation Catalysis of a Ti-Substituted Phosphotungstate, and Identification of the Active Oxygen Species, Catal. Sci. Technol, vol.5, pp.4778-4789, 2015. ,
Chemistry of Group IV Metal Ion-Containing Polyoxometalates, Eur. J. Inorg. Chem, pp.179-196, 2011. ,
DOI : 10.1002/ejic.201000712
Organic-inorganic hybrids based on polyoxometalates. Part IV: A multinuclear magnetic resonance structural investigation, J. Chim. Phys. Phys.-Chim. Biol, vol.95, pp.289-294, 1998. ,
Metal-Catalyzed Oxidations of Organic Compounds ,
In Applied Homogeneous Catalysis with Organometallic Compounds; B ,
Mechanism of the Olefin Epoxidation Catalyzed by Molybdenum Diperoxo Complexes: Quantum-Chemical Calculations Give an Answer to a Long-Standing Question, J. Am. Chem. Soc, vol.122, pp.10101-10108, 2000. ,
On the Mechanism of the Vanadium and Molybdenum Catalyzed Oxidation of Sulphides and Olefins Bearing Neighbour Hydroxo Groups by t-Butyl Hydroperoxide and Hydrogen Peroxide, J. Mol. Catal, vol.19, pp.319-329, 1983. ,
Selective Dihydroxylation over Titanium Silicate Molecular Sieves, J. Catal, vol.176, pp.305-309, 1998. ,
DOI : 10.1006/jcat.1998.2055
Metal Ions Associated to the Molecular Sieve Framework: Possible Catalytic Oxidation Sites, Stud. Surf. Sci. Catal, vol.85, pp.177-213, 1994. ,
DOI : 10.1016/s0167-2991(08)60768-5
Novel Unusually Stable Peroxotitanium(IV) Compounds. Molecular and Crystal Structure Peroxobis(picolinato)(Hexamethylphosphoric triamide)Titanium(IV), Inorg. Chem, vol.21, pp.1303-1306, 1982. ,
DOI : 10.1021/ic00134a004
,
A ?-Oxo-?-? 2 :? 2 -Peroxo Titanium Complex as a Reservoir of Active Species in ,
, Asymmetric Epoxidation Using Hydrogen Peroxide, Angew. Chem. Int. Ed, vol.47, pp.10195-10198, 2008.
The Structure of the Peroxo Species in the TS-1 Catalyst as Investigated by Resonant Raman Spectroscopy, Angew. Chem. Int. Ed, vol.41, pp.4734-4737, 2002. ,
,
Resonance Raman Effects in TS-1: The Structure of Ti(IV) Species and Reactivity towards H 2 O, NH 3 and H 2 O 2 : An in Situ Study, Phys. Chem. Chem. Phys, vol.5, pp.4390-4393, 2003. ,
,
Ti-Peroxo Species in the TS-1/H 2 O 2 /H 2 O System, J. Phys. Chem. B, vol.108, pp.3573-3583, 2004. ,
,
, Surface Species in Heterogeneous Catalysts Probed by In Situ X-Ray Absorption Techniques
, Chem. Rev, vol.113, pp.1736-1850, 2013.
Periodic Trends in Olefin Epoxidation over Group IV and V Framework-Substituted Zeolite Catalysts: A Kinetic and Spectroscopic Study, J. Am. Chem. Soc, vol.139, pp.6888-6898, 2017. ,
DOI : 10.1021/jacs.7b01422
Microporous Crystalline Titanium Silicates, Adv. Catal, vol.41, pp.253-334, 1996. ,
DOI : 10.1016/s0360-0564(08)60042-5
Mechanism of the Decomposition of Aqueous Hydrogen Peroxide over Heterogeneous ,
, Selective Oxidation Catalysts: Insights from Spectroscopic and Density Functional Theory Studies, ACS Catal, vol.1, pp.1665-1678, 2011.
Reactivity of Ti(IV) Species Hosted in TS-1 towards H 2 O 2 -H 2 O Solutions Investigated by Ab Initio Cluster and Periodic Approaches Combined with Experimental XANES and EXAFS Data: A Review and New Highlights, Phys. Chem. Chem. Phys, vol.9, pp.4854-4878, 2007. ,
Photochemical and FT-IR Probing of the Active Site of Hydrogen Peroxide in Ti Silicalite Sieve, J. Am. Chem. Soc, vol.124, pp.9292-9298, 2002. ,
Reaction Progress Kinetic Analysis: A Powerful Methodology for ,
DOI : 10.1201/9781420008357.ch27
, Mechanistic Studies of Complex Catalytic Reactions, Angew. Chem., Int. Ed. Engl, vol.44, pp.4302-4320, 2005.
Kinetic Profiling of Catalytic Organic Reactions as a Mechanistic Tool ,
DOI : 10.1021/jacs.5b05841
, J. Am. Chem. Soc, vol.137, pp.10852-10866, 2015.
Synthesis of Propylene Oxide from Propylene and Hydrogen Peroxide Catalyzed by Titanium Silicalite, J. Catal, vol.129, pp.159-167, 1991. ,
Epoxidation of Lower Olefins with Hydrogen Peroxide and Titanium Silicalite, J. Catal, vol.140, pp.71-83, 1993. ,
DOI : 10.1006/jcat.1993.1069
Heteropolytungstates Containing Elements of the Phosphorus Family with (III) or (V) Oxidation States. Identification of Species X 2 W 19 and XW 9 (X = Phosphorus, Arsenic, Antimony, Bismuth) and Its Relation to XW 11, C R Acad Sci Ser C, vol.277, pp.643-645, 1973. ,
A New Class of Organosilyl Derivatives of ,
, Polyoxoanions -Attachment of Alkyl-and Arylsilyl Groups on Trivacant Tungstosilicate, New J. Chem, vol.15, pp.607-608, 1991.
Some Triple Resonance Experiments in Solid-State CP MAS NMR: V-51/Si-29, P-31/C-13, and Si-29/C-13, Comptes Rendus Chim, vol.9, pp.466-471, 2006. ,
URL : https://hal.archives-ouvertes.fr/hal-00107475
Secondary Organic Aerosol Formation via 2-Methyl-3-buten-2-ol Photooxidation: Evidence of Acid-Catalyzed Reactive Uptake of Epoxides, Environ. Sci. Technol. Lett, vol.1, pp.242-247, 2014. ,
WinGX Suite for Small-Molecule Single-Crystal Crystallography, J. Appl ,
DOI : 10.1107/s0021889899006020
, , vol.32, pp.837-838, 1999.
SUPERFLIP -A Computer Program for the Solution of ,
, Crystal Structures by Charge Flipping in Arbitrary Dimensions, J. Appl. Crystallogr, vol.40, pp.786-790, 2007.