Room temperature reversible C-H activation mediated by a Pt(0) center, and stoichiometric biphenyl formation via solvent activation.

Emmanuel Nicolas; Xavier-Frédéric Le Goff; Stéphane Bouchonnet; Nicolas Mézailles

Room temperature reversible C-H activation mediated by a Pt(0) center, and stoichiometric biphenyl formation via solvent activation.

Emmanuel Nicolas ¹ Xavier-Frédéric Le Goff ¹ Stéphane Bouchonnet ² Nicolas Mézailles ^{1, *}

* Corresponding author

1 DCPH - Laboratoire Hétéroéléments et Coordination

2 DCMR - Laboratoire des mécanismes réactionnels

Abstract : Room temperature reversible C-H activation mediated by a designed diphosphine platinum complex is presented. These findings are demonstrated through mechanistic studies involving kinetics, isotopic effects, and corroborated by DFT calculations. The coupling between two unactivated aromatic derivatives is also demonstrated.

Document type :

Journal articles

Domain :

Chemical Sciences / Inorganic chemistry

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https://hal-polytechnique.archives-ouvertes.fr/hal-00823000
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Submitted on : Wednesday, May 15, 2013 - 10:30:05 PM
Last modification on : Tuesday, July 30, 2019 - 8:26:06 AM
Long-term archiving on : Monday, August 19, 2013 - 4:30:32 PM

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Room temperature reversible C-H activation mediated by a Pt(0) center, and stoichiometric biphenyl formation via solvent activation.

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Room temperature reversible C-H activation mediated by a Pt(0) center, and stoichiometric biphenyl formation via solvent activation.

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389

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