Room temperature reversible C-H activation mediated by a Pt(0) center, and stoichiometric biphenyl formation via solvent activation. - École polytechnique Access content directly
Journal Articles Chemical Communications Year : 2012

Room temperature reversible C-H activation mediated by a Pt(0) center, and stoichiometric biphenyl formation via solvent activation.

Abstract

Room temperature reversible C-H activation mediated by a designed diphosphine platinum complex is presented. These findings are demonstrated through mechanistic studies involving kinetics, isotopic effects, and corroborated by DFT calculations. The coupling between two unactivated aromatic derivatives is also demonstrated.
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hal-00823000 , version 1 (15-05-2013)

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Emmanuel Nicolas, X. F Le Goff, Stéphane Bouchonnet, Nicolas Mézailles. Room temperature reversible C-H activation mediated by a Pt(0) center, and stoichiometric biphenyl formation via solvent activation.. Chemical Communications, 2012, 48 (67), pp.8350-2. ⟨10.1039/c2cc33847e⟩. ⟨hal-00823000⟩
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