Skip to Main content Skip to Navigation
Journal articles

Tip-enhanced Raman scattering: Influence of the tip-surface geometry on optical resonance and enhancement

Bruno Pettinger 1, * Katrin Domke 2 Dai Zhang 3 Gennaro Picardi 4 Rolf Schuster 5
* Corresponding author
1 Physikalische Chemie
FHI - Fritz-Haber-Institut der Max-Planck-Gesellschaft
2 Biosurface Spectroscopy
AMOLF - FOM Institute for Atomic and Molecular Physics
3 Institut für Physikalische und Theoretische Chemie
4 LPICM - Laboratoire de physique des interfaces et des couches minces [Palaiseau]
5 Institut für Physikalische Chemie [Karlsruhe]
Abstract : The tip-sample distance (z) dependence of tip-enhanced Raman scattering (TERS) has been investigated. The intensities of both, the Raman lines and the broad TERS background, exhibit strong decays with increasing z, which are nearly complete within 10 nm withdrawal of the STM tip in z direction. Interestingly, the maximum of the broad Lorentzian-shaped TER background is substantially blue shifted in energy with z. This effect is ascribed to a corresponding blue shift of the energies of localized plasmon modes upon tip retraction. Both experimental results fit very well data of a simple theoretical near-field model.
Keywords : Tip-enhanced Raman spectroscopy Influence of the tip-surface geometry on optical resonance and enhancement Scanning tunneling microscopy Vibrations of adsorbed molécules Single crystal surfaces
Document type :
Journal articles
Complete list of metadata
https://hal-polytechnique.archives-ouvertes.fr/hal-00838021
Contributor : Gennaro Picardi Connect in order to contact the contributor
Submitted on : Monday, June 24, 2013 - 3:52:01 PM
Last modification on : Thursday, October 28, 2021 - 3:42:03 PM

Identifiers

  • HAL Id : hal-00838021, version 1

Collections

CNRS | X | X-PICM | LPICM | X-DEP-PHYS

Citation

Bruno Pettinger, Katrin Domke, Dai Zhang, Gennaro Picardi, Rolf Schuster. Tip-enhanced Raman scattering: Influence of the tip-surface geometry on optical resonance and enhancement. Surface Science, Elsevier, 2009, 603, pp.1335-1341. ⟨hal-00838021⟩

Export

BibTeX TEI DC DCterms EndNote

Share

Metrics

Les métriques sont temporairement indisponibles