A new, centered 32-electron system: the predicted [U@Si20]6−-like isoelectronic series - Archive ouverte HAL Access content directly
Journal Articles Chemical Science Year : 2012

A new, centered 32-electron system: the predicted [U@Si20]6−-like isoelectronic series

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Abstract

In addition to Lewis' octets and Langmuir's 18-electron principle, 32-electron centered systems are possible. We now propose a new, third example on 32e-bonding between a central metal atom and a ligand cage. Moreover, these actinide-filled Si-20 clusters could lead to novel silicon nanostructures.
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Dates and versions

hal-00880181 , version 1 (12-11-2013)

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Jean-Pierre Dognon, Carine Clavaguera, Pekka Pyykko. A new, centered 32-electron system: the predicted [U@Si20]6−-like isoelectronic series. Chemical Science, 2012, 3, pp.2843-2848. ⟨10.1039/c2sc20448g⟩. ⟨hal-00880181⟩
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