A new, centered 32-electron system: the predicted [U@Si20]6−-like isoelectronic series

Jean-Pierre Dognon 1 Carine Clavaguera 2 Pekka Pyykko 3
1 Lab Chim Coordinat Elements F
2 DCMR - Laboratoire des mécanismes réactionnels
3 Univ Helsinki, Dept Chem
Abstract : In addition to Lewis' octets and Langmuir's 18-electron principle, 32-electron centered systems are possible. We now propose a new, third example on 32e-bonding between a central metal atom and a ligand cage. Moreover, these actinide-filled Si-20 clusters could lead to novel silicon nanostructures.
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Submitted on : Tuesday, November 12, 2013 - 4:57:42 PM
Last modification on : Wednesday, March 20, 2019 - 12:12:02 PM

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Jean-Pierre Dognon, Carine Clavaguera, Pekka Pyykko. A new, centered 32-electron system: the predicted [U@Si20]6−-like isoelectronic series. Chemical Science , The Royal Society of Chemistry, 2012, 3, pp.2843-2848. ⟨10.1039/c2sc20448g⟩. ⟨hal-00880181⟩

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