Service interruption on Monday 11 July from 12:30 to 13:00: all the sites of the CCSD (HAL, EpiSciences, SciencesConf, AureHAL) will be inaccessible (network hardware connection).
Skip to Main content Skip to Navigation
Journal articles

A new, centered 32-electron system: the predicted [U@Si20]6−-like isoelectronic series

Abstract : In addition to Lewis' octets and Langmuir's 18-electron principle, 32-electron centered systems are possible. We now propose a new, third example on 32e-bonding between a central metal atom and a ligand cage. Moreover, these actinide-filled Si-20 clusters could lead to novel silicon nanostructures.
Document type :
Journal articles
Complete list of metadata
Contributor : Denis Roura Connect in order to contact the contributor
Submitted on : Tuesday, November 12, 2013 - 4:57:42 PM
Last modification on : Tuesday, May 3, 2022 - 6:26:04 PM




Jean-Pierre Dognon, Carine Clavaguera, Pekka Pyykko. A new, centered 32-electron system: the predicted [U@Si20]6−-like isoelectronic series. Chemical Science , The Royal Society of Chemistry, 2012, 3, pp.2843-2848. ⟨10.1039/c2sc20448g⟩. ⟨hal-00880181⟩



Record views