Cobalt-Catalyzed Electrophilic Amination of Arylzincs with N-Chloroamines

Xin Qian; Zailu Yu; Audrey Auffrant; C. Gosmini

doi:10.1002/chem.201300229

Journal articles

Cobalt-Catalyzed Electrophilic Amination of Arylzincs with N-Chloroamines

Xin Qian ¹ Zailu Yu ¹ Audrey Auffrant ¹ C. Gosmini ^{1, *}

* Corresponding author

1 DCPH - Laboratoire Hétéroéléments et Coordination

Abstract : An efficient cobalt-catalyzed electrophilic amination of arylzinc reagents has been achieved. A variety of functionalized arylzincs and N-chloroamines were coupled under mild conditions (see scheme). Both secondary and tertiary arylamines were obtained in moderate to excellent yields.

Keywords : amination anilines C[BOND]N coupling cobalt zinc

Document type :

Journal articles

Domain :

Chemical Sciences / Coordination chemistry

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https://hal-polytechnique.archives-ouvertes.fr/hal-00906334
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Submitted on : Tuesday, November 19, 2013 - 3:33:19 PM
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Cobalt-Catalyzed Electrophilic Amination of Arylzincs with N-Chloroamines

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Cobalt-Catalyzed Electrophilic Amination of Arylzincs with N-Chloroamines

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