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Cobalt-Catalyzed Electrophilic Amination of Arylzincs with N-Chloroamines

Xin Qian 1 Zailu Yu 1 Audrey Auffrant 1 C. Gosmini 1, *
* Corresponding author
1 DCPH - Laboratoire Hétéroéléments et Coordination
Abstract : An efficient cobalt-catalyzed electrophilic amination of arylzinc reagents has been achieved. A variety of functionalized arylzincs and N-chloroamines were coupled under mild conditions (see scheme). Both secondary and tertiary arylamines were obtained in moderate to excellent yields.
Keywords : amination anilines C[BOND]N coupling cobalt zinc
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https://hal-polytechnique.archives-ouvertes.fr/hal-00906334
Contributor : Francoise Girard <>
Submitted on : Tuesday, November 19, 2013 - 3:33:19 PM
Last modification on : Tuesday, November 24, 2020 - 4:40:04 PM

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Xin Qian, Zailu Yu, Audrey Auffrant, C. Gosmini. Cobalt-Catalyzed Electrophilic Amination of Arylzincs with N-Chloroamines. Chemistry - A European Journal, Wiley-VCH Verlag, 2013, 19 (20), pp.6225-6229. ⟨10.1002/chem.201300229⟩. ⟨hal-00906334⟩

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