Service interruption on Monday 11 July from 12:30 to 13:00: all the sites of the CCSD (HAL, Epiciences, SciencesConf, AureHAL) will be inaccessible (network hardware connection).
Skip to Main content Skip to Navigation
Journal articles

A highly stereoselective, modular route to (E)-vinylsulfones and to (Z)- and (E)-alkenes

Abstract : A recently discovered radical fragmentation of 2-fluoro-6-pyridinoxy derivatives allows a new highly stereoselective and convergent route to (E)-vinylsulfones from allylic alcohols. Reductive desulfonylation or nickel-catalyzed couplings furnish di- and trisubstituted (E)- and (Z)-alkenes. © 2011 American Chemical Society.
Document type :
Journal articles
Complete list of metadata
Contributor : Denis Roura Connect in order to contact the contributor
Submitted on : Tuesday, February 25, 2014 - 9:57:12 PM
Last modification on : Thursday, December 9, 2021 - 2:26:02 PM




Marie-Gabrielle Braun, Béatrice Quiclet-Sire, Samir Z. Zard. A highly stereoselective, modular route to (E)-vinylsulfones and to (Z)- and (E)-alkenes. Journal of the American Chemical Society, American Chemical Society, 2011, 133 (40), pp.15954-15957. ⟨10.1021/ja207944c⟩. ⟨hal-00950008⟩



Record views