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A highly stereoselective, modular route to (E)-vinylsulfones and to (Z)- and (E)-alkenes

Abstract : A recently discovered radical fragmentation of 2-fluoro-6-pyridinoxy derivatives allows a new highly stereoselective and convergent route to (E)-vinylsulfones from allylic alcohols. Reductive desulfonylation or nickel-catalyzed couplings furnish di- and trisubstituted (E)- and (Z)-alkenes. © 2011 American Chemical Society.
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Marie-Gabrielle Braun, Béatrice Quiclet-Sire, Samir Zard. A highly stereoselective, modular route to (E)-vinylsulfones and to (Z)- and (E)-alkenes. Journal of the American Chemical Society, American Chemical Society, 2011, 133 (40), pp.15954-15957. ⟨10.1021/ja207944c⟩. ⟨hal-00950008⟩



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