A highly stereoselective, modular route to (E)-vinylsulfones and to (Z)- and (E)-alkenes

Marie-Gabrielle Braun; Béatrice Quiclet-Sire; Samir Zard

A highly stereoselective, modular route to (E)-vinylsulfones and to (Z)- and (E)-alkenes

Marie-Gabrielle Braun ¹ Béatrice Quiclet-Sire ¹ Samir Zard ¹

1 DCSO - Laboratoire de synthèse organique

Abstract : A recently discovered radical fragmentation of 2-fluoro-6-pyridinoxy derivatives allows a new highly stereoselective and convergent route to (E)-vinylsulfones from allylic alcohols. Reductive desulfonylation or nickel-catalyzed couplings furnish di- and trisubstituted (E)- and (Z)-alkenes. © 2011 American Chemical Society.

Document type :

Journal articles

Domain :

Chemical Sciences / Organic chemistry

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https://hal-polytechnique.archives-ouvertes.fr/hal-00950008
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Submitted on : Tuesday, February 25, 2014 - 9:57:12 PM
Last modification on : Thursday, February 7, 2019 - 5:20:27 PM

A highly stereoselective, modular route to (E)-vinylsulfones and to (Z)- and (E)-alkenes

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A highly stereoselective, modular route to (E)-vinylsulfones and to (Z)- and (E)-alkenes

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