Gold(l)-catalyzed formation of furans by a Claisen type rearrangement of ynenyl allyl ethers

Abstract : A series of ynenyl allyl ethers were rearranged into polysubstituted furans in the presence of a gold(I) catalyst. It is proposed that the transformation involves a Claisen-type rearrangement that allows the efficient creation of quaternary centers under mild experimental conditions. © 2011 Istrate and Gagosz.
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Florin Istrate, Fabien Gagosz. Gold(l)-catalyzed formation of furans by a Claisen type rearrangement of ynenyl allyl ethers. Beilstein Journal of Organic Chemistry, Beilstein-Institut, 2011, 7, pp.878-885. ⟨10.3762/bjoc.7.100⟩. ⟨hal-00950027⟩

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