Gold(l)-catalyzed formation of furans by a Claisen type rearrangement of ynenyl allyl ethers

Florin Istrate; Fabien Gagosz

Gold(l)-catalyzed formation of furans by a Claisen type rearrangement of ynenyl allyl ethers

Florin Istrate ¹ Fabien Gagosz ^{1, *}

* Corresponding author

1 DCSO - Laboratoire de synthèse organique

Abstract : A series of ynenyl allyl ethers were rearranged into polysubstituted furans in the presence of a gold(I) catalyst. It is proposed that the transformation involves a Claisen-type rearrangement that allows the efficient creation of quaternary centers under mild experimental conditions. © 2011 Istrate and Gagosz.

Document type :

Journal articles

Domain :

Chemical Sciences / Organic chemistry

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Gold(l)-catalyzed formation of furans by a Claisen type rearrangement of ynenyl allyl ethers

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Gold(l)-catalyzed formation of furans by a Claisen type rearrangement of ynenyl allyl ethers

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