Synthesis of functionalized furans via gold(I)-catalyzed Claisen-type rearrangement

Abstract : (Chemical Equation Presented) Gold(I)-catalyzed cyclization of pentenynyl allyl ethers allows the rapid construction of functionalized furans. The concerted oxy-Claisen-type mechanism induces a complete selectivity of the process and allows the easy formation of quaternary centers. © 2008 American Chemical Society.
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Florin Istrate, Fabien Gagosz. Synthesis of functionalized furans via gold(I)-catalyzed Claisen-type rearrangement. Journal of Organic Chemistry, American Chemical Society, 2008, 73 (2), pp.730-733. ⟨10.1021/jo7022685⟩. ⟨hal-00951290⟩

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