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Gold(I) catalyzed isomerization of 5-en-2-yn-1-yl acetates: An efficient access to acetoxy bicyclo[3.1.0]hexenes and 2-cycloalken-1-ones
Abstract : The gold(I) catalyzed rearrangement of 5-en-2-yn-1-yl acetates into functionalized acetoxy bicyclo[3.1.0]hexenes is described. The mild reaction conditions employed allow the efficient and rapid synthesis of a variety of such bicyclic compounds via a sequence of two gold(I)-catalyzed isomerization steps. Acetoxy bicyclo[3.1.0]hexenes products can be further transformed to 2-cycloalkenones by simple methanolysis. Copyright © 2006 American Chemical Society.
https://hal-polytechnique.archives-ouvertes.fr/hal-00951310
Contributor : Denis Roura <>
Submitted on : Monday, March 3, 2014 - 3:08:12 PM
Last modification on : Thursday, March 5, 2020 - 6:25:23 PM
Contributor : Denis Roura <>
Submitted on : Monday, March 3, 2014 - 3:08:12 PM
Last modification on : Thursday, March 5, 2020 - 6:25:23 PM
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