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Total synthesis of 10-norparvulenone and of O-methylasparvenone using a xanthate-mediated free radical addition - Cyclization sequence

Alejandro Cordero Vargas 1 Béatrice Quiclet-Sire 1 Samir Zard 1
1 DCSO - Laboratoire de synthèse organique
Abstract : (Matrix presented) A short synthesis of (±)-10-norparvulenone and (±)-O-methylasparvenone was developed starting from commercially available m-methoxyphenol, hinging on a xanthate-mediated addition - cyclization sequence for the construction of the a-tetralone subunit.
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https://hal-polytechnique.archives-ouvertes.fr/hal-00954833
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Submitted on : Tuesday, March 18, 2014 - 9:14:03 PM
Last modification on : Thursday, December 9, 2021 - 2:26:02 PM

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CNRS | X-DCSO | X | INC-CNRS | X-DEP-CHIM

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Alejandro Cordero Vargas, Béatrice Quiclet-Sire, Samir Zard. Total synthesis of 10-norparvulenone and of O-methylasparvenone using a xanthate-mediated free radical addition - Cyclization sequence. Organic Letters, American Chemical Society, 2003, 5 (20), pp.3717-3719. ⟨10.1021/ol035394o⟩. ⟨hal-00954833⟩

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