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ß-nitro xanthates as olefin precursors

Abstract : (Matrix presented) Potassium O-ethyl xanthate readily adds to a,ß-unsaturated nitro compounds to give stable ß-nitro xanthates, which undergo tin-free elimination to form olefins in good yield and good E selectivity upon simple heating with lauroyl peroxide in refluxing 1,2-dichloroethane.
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https://hal-polytechnique.archives-ouvertes.fr/hal-00954834
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Submitted on : Tuesday, March 18, 2014 - 9:16:28 PM
Last modification on : Thursday, March 5, 2020 - 6:25:47 PM

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Gilles Ouvry, Béatrice Quiclet-Sire, Samir Zard. ß-nitro xanthates as olefin precursors. Organic Letters, American Chemical Society, 2003, 5 (16), pp.2907-2909. ⟨10.1021/ol035027c⟩. ⟨hal-00954834⟩

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