A New, Simple, and Selective Palladium-Catalyzed Cleavage of Triethylsilyl Ethers

Abstract : (Equation Presented) A simple procedure for the cleavage of triethylsilyl (TES) ethers in the presence of 10 wt % Pd/C in methanol or 95% ethanol is reported. This method allows selective removal of alkyl TES ethers in the presence of aromatic TES ethers or tert-butyldimethylsilyl (TBS) protecting groups.
Document type :
Journal articles
Complete list of metadatas

https://hal-polytechnique.archives-ouvertes.fr/hal-00954849
Contributor : Denis Roura <>
Submitted on : Tuesday, March 18, 2014 - 8:44:36 PM
Last modification on : Thursday, February 7, 2019 - 5:16:40 PM

Identifiers

Collections

Citation

Delphine Rotulo-Sims, Joëlle Prunet. A New, Simple, and Selective Palladium-Catalyzed Cleavage of Triethylsilyl Ethers. Organic Letters, American Chemical Society, 2002, 4 (26), pp.4701-4704. ⟨10.1021/ol0271382⟩. ⟨hal-00954849⟩

Share

Metrics

Record views

124