The Cl2(PCy3)(IMes)Ru(=CHPh) catalyst: Olefin metathesis versus olefin isomerization - Archive ouverte HAL Access content directly
Journal Articles Journal of Organometallic Chemistry Year : 2002

The Cl2(PCy3)(IMes)Ru(=CHPh) catalyst: Olefin metathesis versus olefin isomerization

(1) , (2) , (3) , (1)
1
2
3

Abstract

While investigating RCM of substrates requiring elevated temperatures and extended reaction times, significant isomerization of one of the double bonds in the starting diene was observed with the recently developed [RuIMes] catalyst. This isomerization appeared as an important drawback of the catalyst, but a judicious selection of solvent and additive can completely eliminate this side reaction. © 2002 Elsevier Science B.V. All rights reserved.

Dates and versions

hal-00954863 , version 1 (17-03-2014)

Identifiers

Cite

Damien Bourgeois, A. Pancrazi, S.P. Nolan, Joëlle Prunet. The Cl2(PCy3)(IMes)Ru(=CHPh) catalyst: Olefin metathesis versus olefin isomerization. Journal of Organometallic Chemistry, 2002, 643-644 (-), pp.247-252. ⟨10.1016/s0022-328x(01)01269-4⟩. ⟨hal-00954863⟩
120 View
0 Download

Altmetric

Share

Gmail Facebook Twitter LinkedIn More