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The Cl2(PCy3)(IMes)Ru(=CHPh) catalyst: Olefin metathesis versus olefin isomerization
Abstract : While investigating RCM of substrates requiring elevated temperatures and extended reaction times, significant isomerization of one of the double bonds in the starting diene was observed with the recently developed [RuIMes] catalyst. This isomerization appeared as an important drawback of the catalyst, but a judicious selection of solvent and additive can completely eliminate this side reaction. © 2002 Elsevier Science B.V. All rights reserved.
https://hal-polytechnique.archives-ouvertes.fr/hal-00954863
Contributor : Denis Roura Connect in order to contact the contributor
Submitted on : Monday, March 17, 2014 - 9:20:38 PM
Last modification on : Thursday, December 9, 2021 - 2:26:02 PM
Contributor : Denis Roura Connect in order to contact the contributor
Submitted on : Monday, March 17, 2014 - 9:20:38 PM
Last modification on : Thursday, December 9, 2021 - 2:26:02 PM
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