The Cl2(PCy3)(IMes)Ru(=CHPh) catalyst: Olefin metathesis versus olefin isomerization

Damien Bourgeois 1 A. Pancrazi 2 S.P. Nolan 3 Joëlle Prunet 1
1 DCSO - Laboratoire de synthèse organique
2 Laboratoire de Synthèse Organique
3 Department of Chemistry
Abstract : While investigating RCM of substrates requiring elevated temperatures and extended reaction times, significant isomerization of one of the double bonds in the starting diene was observed with the recently developed [RuIMes] catalyst. This isomerization appeared as an important drawback of the catalyst, but a judicious selection of solvent and additive can completely eliminate this side reaction. © 2002 Elsevier Science B.V. All rights reserved.
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Journal of Organometallic Chemistry, Elsevier, 2002, 643-644 (-), pp.247-252. 〈10.1016/s0022-328x(01)01269-4〉
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Contributeur : Denis Roura <>
Soumis le : lundi 17 mars 2014 - 21:20:38
Dernière modification le : jeudi 10 mai 2018 - 02:07:32

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Damien Bourgeois, A. Pancrazi, S.P. Nolan, Joëlle Prunet. The Cl2(PCy3)(IMes)Ru(=CHPh) catalyst: Olefin metathesis versus olefin isomerization. Journal of Organometallic Chemistry, Elsevier, 2002, 643-644 (-), pp.247-252. 〈10.1016/s0022-328x(01)01269-4〉. 〈hal-00954863〉

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