Xanthates and solid-phase chemistry. A new soluble polymer analogue of Wang resin

Anne-Claude Dublanchet (1, 2) , Marie Lusinchi (1, 2) , Samir Z. Zard (1, 2)

1 Department of Chemistry
2 DCSO - Laboratoire de synthèse organique

The straightforward synthesis of a new soluble polymer containing a Wang type linker is described. Inter-molecular radical additions of xanthates onto olefins were performed with this new resin in comparison with a classical Wang resin. The new soluble polymer analogue of Wang resin allows easy H-1 monitoring of the reactions and gives better results for the radical transfer while preserving the efficient cleavage conditions of the Wang linker. (C) 2002 Published by Elsevier Science Ltd.

Anne-Claude Dublanchet, Marie Lusinchi, Samir Z. Zard. Xanthates and solid-phase chemistry. A new soluble polymer analogue of Wang resin. Tetrahedron, 2002, 58 (28), pp.5715-5721. ⟨10.1016/s0040-4020(02)00526-4⟩. ⟨hal-00954864⟩