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Abstract : The present communication deals with several recent developments of the MADIX process, including (i) the removal of the xanthate terminal group (detailed by the authors in two separate preprints of this volume) (ii) the use of a fluorinated xanthate in ab initio emulsion polymerization (iii) the synthesis of hydrid block copolymers comprising a poly(dimethyl siloxane) or a polyolefin block. The latest results of our group confirm the versatility of the MADIX process to produce a broad range of polymers with controlled architectures in homogeneous or dispersed media.
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https://hal-polytechnique.archives-ouvertes.fr/hal-00965879 Contributor : Denis RouraConnect in order to contact the contributor Submitted on : Tuesday, March 25, 2014 - 5:16:01 PM Last modification on : Thursday, December 9, 2021 - 2:26:02 PM
Mathias Destarac, Wojciech Bzducha, Samir Z. Zard. Recent advances in the MADIX process. Controlled/living Radical Polymerization Symposium, The 230th ACS National Meeting, Aug 2005, Washington, United States. pp.POLY 730. ⟨hal-00965879⟩