A Method for the Contra-thermodynamic Isomerization of Cyclic Trisubstituted Alkenes

Abstract : A simple sequence for the net contra-thermodynamic isomerization of cyclic trisubstituted alkenes is reported consisting of a radical addition of p-chlorothiophenol, followed by oxidation to the sulfoxide and thermal syn-elimination to give the least substituted isomeric cycloalkene.
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Article dans une revue
Organic Letters, American Chemical Society, 2013, 15 (16), pp.4178-4181. 〈10.1021/ol4018744〉
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Soumis le : mercredi 26 mars 2014 - 21:37:35
Dernière modification le : jeudi 10 mai 2018 - 02:07:54

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Raphaël Guignard, Laurent Petit, Samir Zard. A Method for the Contra-thermodynamic Isomerization of Cyclic Trisubstituted Alkenes. Organic Letters, American Chemical Society, 2013, 15 (16), pp.4178-4181. 〈10.1021/ol4018744〉. 〈hal-00966611〉

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