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Journal Articles Organic Letters Year : 2013

A Method for the Contra-thermodynamic Isomerization of Cyclic Trisubstituted Alkenes

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Abstract

A simple sequence for the net contra-thermodynamic isomerization of cyclic trisubstituted alkenes is reported consisting of a radical addition of p-chlorothiophenol, followed by oxidation to the sulfoxide and thermal syn-elimination to give the least substituted isomeric cycloalkene.
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hal-00966611 , version 1 (26-03-2014)

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Raphaël F. Guignard, Laurent Petit, Samir Z. Zard. A Method for the Contra-thermodynamic Isomerization of Cyclic Trisubstituted Alkenes. Organic Letters, 2013, 15 (16), pp.4178-4181. ⟨10.1021/ol4018744⟩. ⟨hal-00966611⟩
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