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Journal articles
A two-step synthesis of α-keto vinyl carbinols from ketones.
Abstract : Conjugate addition of lithium enolates onto terminal alkynyl- and allenyl-sulfoxides furnishes the corresponding allylic sulfoxides. The latter readily undergo a Mislow-Braverman-Evans rearrangement to yield the targeted α-keto vinyl carbinols. This two-step procedure does not require purification of the intermediates and constitutes the shortest approach to α-keto vinyl carbinols.
https://hal-polytechnique.archives-ouvertes.fr/hal-00966612
Contributor : Denis Roura <>
Submitted on : Wednesday, March 26, 2014 - 9:39:01 PM
Last modification on : Thursday, March 5, 2020 - 6:26:55 PM
Contributor : Denis Roura <>
Submitted on : Wednesday, March 26, 2014 - 9:39:01 PM
Last modification on : Thursday, March 5, 2020 - 6:26:55 PM