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The total synthesis of (+/-)-fortucine and a revision of the structure of kirkine.
Abstract : The total synthesis of the natural product fortucine relies on a radical cascade process initiated by the generation of a nitrogen-centered (amidyl) radical (see picture). The procedure is concise, and tin-free, as well as stereo- and regioselective. This synthesis has enabled the correction of the structure of kirkine, and the strategy represents a general and rapid entry into the galanthan framework.
https://hal-polytechnique.archives-ouvertes.fr/hal-00969141
Contributor : Denis Roura <>
Submitted on : Wednesday, April 2, 2014 - 10:31:05 AM
Last modification on : Tuesday, November 3, 2020 - 9:50:04 AM
Contributor : Denis Roura <>
Submitted on : Wednesday, April 2, 2014 - 10:31:05 AM
Last modification on : Tuesday, November 3, 2020 - 9:50:04 AM
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