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Journal articles

Xanthate-Mediated Incorporation of Quaternary Centers into Heteroarenes

Abstract : The xanthate-mediated addition of tertiary alkyl radicals to heteroarenes enabled the easy functionalization of heteroaromatic rings as well as more decorated structures, such as marketed drugs or agrochemicals. This work provides a synthetic tool for efficiently exploring the chemical space by allowing late-stage diversification with a high tolerance toward functional groups.
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Contributor : Aurélien Arnoux Connect in order to contact the contributor
Submitted on : Tuesday, April 9, 2019 - 3:48:43 PM
Last modification on : Tuesday, January 4, 2022 - 4:01:01 AM





Vincent Revil-Baudard, Jean-Pierre Vors, Samir Z. Zard. Xanthate-Mediated Incorporation of Quaternary Centers into Heteroarenes. Organic Letters, American Chemical Society, 2018, 20 (12), pp.3531-3535. ⟨10.1021/acs.orglett.8b01299⟩. ⟨hal-02094367⟩



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