Free-radical variant for the synthesis of functionalized 1,5-diketones.

Abstract : A free-radical approach for the synthesis of functionalized 1,5-diketones has been accomplished through an effective combination play between alkenylacylphosphonates and keto-xanthates as radical surrogates of enolates and enones, respectively.
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Submitted on : Wednesday, March 26, 2014 - 9:34:15 PM
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Kelvin Kau Kiat Goh, Sunggak Kim, Samir Z Zard. Free-radical variant for the synthesis of functionalized 1,5-diketones.. Organic Letters, American Chemical Society, 2013, 15 (18), pp.4818-4821. ⟨10.1021/ol402213k⟩. ⟨hal-00966610⟩

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