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Phosphahelicenes: from chiroptical and photophysical properties to OLED applications

Abstract : Herein, the experimental physicochemical and chiroptical properties of a series of phosphahelicenes are reported, focusing on their UV/Vis absorption, luminescence, electronic circular dichroism, optical rotations, and circularly polarized luminescence. Furthermore, detailed analysis of absorption and ECD spectra performed with the help of quantum-chemical calculations allowed us to highlight general features of these helicenic phosphines. Finally, due to well-suited electrochemical properties and thermal stability, the systems were successfully used as emitters in organic light-emitting diodes.
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Contributor : Pierre-Antoine Bouit <>
Submitted on : Thursday, February 7, 2019 - 1:43:09 PM
Last modification on : Thursday, March 5, 2020 - 6:34:44 PM
Document(s) archivé(s) le : Wednesday, May 8, 2019 - 3:52:11 PM


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Keihann Yavari, Wylliam Delaunay, Nicolas de Rycke, Thibault Reynaldo, Paul Aillard, et al.. Phosphahelicenes: from chiroptical and photophysical properties to OLED applications. Chemistry - A European Journal, Wiley-VCH Verlag, 2019, 25 (20), pp.5303-5310. ⟨10.1002/chem.201806140⟩. ⟨hal-02010723⟩



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