Phosphahelicenes: from chiroptical and photophysical properties to OLED applications

Abstract : Herein, we report experimental physico chiroptical properties of a series of phosphahelicenes, their UV/Vis absorption, luminescence, electronic (ECD), optical rotations, and circularly polarized luminescence Furthermore, detailed analysis of absorption and ECD performed with the help of quantum-chemical calculations us to highlight general features of these heli Finally, due to well-suited electrochemical properties stability, the systems were successfully used as light-emitting diodes.
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Submitted on : Thursday, February 7, 2019 - 1:43:09 PM
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Keihann Yavari, Wylliam Delaunay, Nicolas de Rycke, Thibault Reynaldo, Paul Aillard, et al.. Phosphahelicenes: from chiroptical and photophysical properties to OLED applications. Chemistry - A European Journal, Wiley-VCH Verlag, 2019, 25 (20), pp.5303-5310. ⟨10.1002/chem.201806140⟩. ⟨hal-02010723⟩



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