Palladium-catalysed O -Allylation of α-Hydroxyphosphonates: An Expedient Entry into Phosphono-oxaheterocycles - École polytechnique Access content directly
Journal Articles Advanced Synthesis and Catalysis Year : 2018

Palladium-catalysed O -Allylation of α-Hydroxyphosphonates: An Expedient Entry into Phosphono-oxaheterocycles

Abstract

We report here an unprecedented palladium‐catalysed O‐allylation of α‐hydroxyphosphonates. The method was eventually included in a sequential Pudovik/Tsuji‐Trost type O‐allylation/Ring‐Closing Metathesis to afford a variety of phosphorylated heterocycles of various sizes ranging from 5 to 16 starting from readily available aldehydes.

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hal-02091718 , version 1 (06-04-2019)

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Mansour Dolé Kerim, Martin Cattoen, Nicolas Fincias, Aurélie Dos santos, Stellios Arseniyadis, et al.. Palladium-catalysed O -Allylation of α-Hydroxyphosphonates: An Expedient Entry into Phosphono-oxaheterocycles. Advanced Synthesis and Catalysis, 2018, 360 (3), pp.449-454. ⟨10.1002/adsc.201701150⟩. ⟨hal-02091718⟩
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